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The alkali metals

The alkali metals are found to the far left in the periodic table.The alkali metals are found to the far left in the periodic table.

The alkali metals are:

  • (Hydrogen, H)
  • Lithium, Li
  • Sodium, Na
  • Potassium, K
  • Rubidium, Rb
  • Cesium, Cs
  • Francium, Fr

Alkali metals have one valence electron. Example: 3Li

  K L
3p+ 2e 1e

Oxidation of alkali metals

Alkali metals give off their single valence electron.

When sodium is oxidized, it loses an electron and turns into a sodium ion, Na⁺.When sodium is oxidized, it loses an electron and turns into a sodium ion, Na+.

When the alkali metal atom is oxidized, it gets

  1. a single positive charge, e.g. Na+.
  2. noble gas configuration (eight valence electrons).

The most reactive alkali metal

The furter away from the nucleus,

  • the easier it is to release the valence electron
  • the less energy is needed for ionization (the lower ionization energy).

The reactivity increases downwards in group 1:

  • In francium, the valence electron is in the 7th shell ⇒ very easily given off!
  • In lithium, the valence electron is in the 2nd shell ⇒ not given off as easily.

The halogens (salt producers)

Metals readily react with halogens, producing salts.

  • Example: Sodium reacts with chlorine

    2Na + Cl2 → 2NaCl

The halogens are found in group 17 of the periodic table.The halogens are found in group 17 of the periodic table.

The halogens are:

  • Fluorine, F
  • Chlorine, Cl
  • Bromine, Br
  • Iodine, I
  • Astatine, At
  • Tennessine, Ts

Halogens have seven valence elctrons. Example: 9F

  K L
9p+ 2e 7e

Reduction of halogens

Halogens take up an electron to get noble gas configuration.

When chlorine is reduced it gains an electron and turns into a chloride ion, Cl⁻.When chlorine is reduced it gains an electron and turns into a chloride ion, Cl.

When the halogen atom is reduced, it gets

  1. a single negative charge, e.g. Cl.
  2. noble gas configuration (eight valence electrons).

The most reactive halogen

The closer to the nucleus

  • the easier it is to take up an electron
  • the more energy is given off when that electron is taken up.

The reactivity increases upwards in group 17:

  • In fluorine, the valence electrons are in the 2nd shell ⇒ very easily takes up an electron!
  • In iodine, the valence electrons are in the 5th shell ⇒ electrons aren’t taken up as easily.
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