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Atomic number

Each element has its own number: an atom number.

  • The number of protons in the nucleus decides which element it is.
  • The atom number = the number of protons.

Examples

Element  Atomic number  Number of p+
Hydrogen (H) 1 1
Helium (He) 2 2
Carbon (C) 6 6
Chlorine (Cl) 17 17

Mass number

Every element (except hydrogen) also contains neutrons.

  • Mass number = number of protons + number of neutrons
    • \(A = Z + N\)

Two definitions

  • Nuclide: An atomic species with a certain number of p+ and n.
  • Isotopes: Different nuclides of the same element

The universe's most simple nuclide.The universe's most simple nuclide.

Some isotopes and their mass numbers

Isotope   Nuclide   Atomic nr.   p+   n   mass number 
Hydrogen
\( ^1_1\)H
1 1 0 1
Deuterium \( ^2_1\)H 1 1 1 2
Tritium \( ^3_1\)H 1 1 2 3
Helium
\( ^4_2\)He
2 2 2 4
Carbon-12
\( ^{12}_6\)C
6 6 6 12
Carbon-13
\( ^{13}_{\text{ }\text{ }6}\)C
6 6 7 13
Carbon-14
\( ^{14}_{\text{ }\text{ }6}\)C
6 6 8 14
Chlorine-35
\( ^{35}_{17}\)Cl
17 17 18 35
Chlorine-37
\( ^{35}_{17}\)Cl
17 17 20 37

Atomic mass

A single carbon-12 atom weighs 1.994×10–23 g

  • Cumbersome figure!

The unified atomic mass unit ”u” (sometimes "amu") has been defined:

  • A single carbon-12 atom weighs exactly 12u: 
  • \(m_{^{12}_{\text{ }\text{ }6}\text{C}}\equiv 12\text{u}\)

Also note: 1u = 1Da

How much do the building blocks of the atom weigh?

  • 1 proton weighs approx. 1 u
  • 1 neutron weighs approx. 1 u
  • 1 electron weighs approx. 1/1800 u

The atomic mass of chlorine

  • The atomic mass of chlorine: 35.453u ≈ 35.5u
  • There are two chlorine isotopes: chlorine-35 (75 %) and chlorine-37 (25 %)
  • The average atomic mass of chlorine:

    \[0.75 \times 35\text{u} + 0.25 \times 37\text{u} = 35.5\text{u}\]
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